I bought one from a shop many years back, and my experience was similar to
Roseway's , the nearby wall got gradually covered with very fine dirt/soot from the air. So I suppose it was achieving something!
I also worked in an office where the secretary had one of these near her computer, and when some fault developed on said PC, the ioniser was blamed and removed. Could well have been a case of "blame the nearest unusual thing" though.
Ian