Do you actually recommend me trying to make my ISP change my connection to PPPoA for increase performance? or the difference is so small comparing both?
PPPoA has a slight edge over PPPoE in terms of packet size (due to the PPPoE 8 byte header overhead). The difference is infinitesimal and depends on the overall size of the payload and the number of packets it takes to transmit it. Over a long period of time you may be able to measure a difference, but we're talking about a few additional packets here and there. So theoretically, PPPoA is marginally more efficient because (depending on the size of the payload) it can transmit the same data using fewer packets than PPPoE.
On the other hand, if your router and the telephone exchange equipment support it you can configure your router to use 'baby giant frames' (with an mtu of 1508) so that the full 1500 byte packet can be transmitted with PPPoE without fragmentation. If not, then you better set the mtu for your router and the PCs in your LAN to the default PPPoE size of 1492 bytes.
Personally, I think that a better quality, high throughput/low latency router will give you a much more noticeable difference in performance than a PPPoA Vs PPPoE connection ever will (as long as you have set up your mtu correctly on your network).
HTH.