Yeah its staying blocked, but was curious of the cause, which I have now found.
Its VLC media player, there is an option in there to toggle SMB protocol, but nothing in there to disable it, uninstalling the app.
The app has been on my phone for ages, but today was one clip which needed VLC to play, I played it in VLC and since then for hours every 6 seconds the UDP 137 traffic.
Replaced it with MPV.