I believe between 02:00 & 06:00 are the usual times, but I have seen what appear to be DLM resyncs occur at other times (both earlier & later).
This is the timing of my most recent 'DLM' resync:-
08/10/2014 00:45 - RESYNC detected (DS 22399 Kbps, US 4295 Kbps), AS = 37, Retrain Reason: 1
The resync must have occured during the previous minute as the AS value = 37 at the time the data was harvested at a few seconds past 00:45
FWIW, 8 DS LOF & 1 LOS delta values were reported following the resync.