Over the years TT have taken over many other SP networks and at least for a while (years) left the old network more or less 'as was'. It was tiscali (and the TT /ex Tiscali ) part of their network that would only work using pppoa, vcmux.
Btw the BTW network will also work when the router is set up as pppoe. As confirmed in about 2006 when plusnet moved some of their customers to tiscali retail network and suddenly their connection no longer worked.
The reason was as a result of many routers auto configs... What happens is during auto config, the router tries pppoe first and if it works continues to use it, if it doesn't it tries pppoa. Whilst BT is actually pppoa, it also allows pppoe by emulating pppoe (PPPoEoA). The solution for PN /tiscali LLU customers was to simply manually set their router to pppoa.